in. Every boron trifluoride valve is equipped with a device consisting of a platinum disc in back of a plug containing a metal that will melt at approx 70 °C. C: 0.7 ppm Section 8. 0000004589 00000 n Boron trichloride - Wikipedia new en.wikipedia.org. NIOSH REL: 1 ppm (3 mg/m3) CEILING. NO water. Carbon tetrachloride, also known by many other names (such as tetrachloromethane, also recognised by the IUPAC, carbon tet in the cleaning industry, Halon-104 in firefighting, and Refrigerant-10 in HVACR) is an organic compound with the chemical formula CCl 4.It is a colourless liquid with a "sweet" smell that can be detected at low levels. $60.00 Aldrich-295019; Boron trichloride 0.999; CAS Number: 10294-34-5; Linear Formula: BCl3; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. oF8���� �t� ���I��u��[���3F�����~G�)W{�l��cB���s@q�Z�� �*���n�$0\�*=�!g��lW� �|�"hw!�t�x��H�����Ro�,������/Q`�d���{�����>�Z"�84 w�������k��Rx)�����XC. �4�[(�R�=�@(�)U�����o������D@��A�TU���bȕi�PI��m����h This equipment efficiently renders the various toxic gases emitted during the semiconductor manufacturing process chemically and physically harmless. Sub. Be sure to use an approved/certified respirator or equivalent. Hazards Identification Toxic, corrosive liquid and gas under pressure. 1008 125. Praxair recommends compliance with the OSHA and ACGIH (2000) limits of 5 ppm (ceiling) for hydrogen chloride, formed by the hydrolysis of boron trichloride. #��w�C��w&tص�@H���m�w���Rc �>�r�zZ�!�/y��J��~��5�t Flash Point Nonflammable TLV 1 ppm Boiling Point 91.3°C @ 760mm Hg Freezing Point -46°C APPLICATIONS Liquid boron source used in p-type deposition processes Replaces diborane (B2H6) and boron trichloride (BCl3) BBr3 oxidizes at process temperatures to form B2O3. The similarity in toxicity values for boron trifluoride and boron trichloride with the hydrolysis products tends to support limited hydrolysis. Personal Protection in Case of a Large Spill: Splash goggles. This reaction can also be done with dry B4C in a fluidized-bed reactor using a transition-metal halide as a catalyst. ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Not combustible. UBE RID . Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) Boron trifluoride diethyletherate TWA: 0.1 ppm Ceiling: 0.7 ppm Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration Engineering Measures Use only under a chemical fume hood. f This chemical is on the Special Health Hazard Substance List. Boron trichloride is the inorganic compound with the formula BCl 3. 0000020593 00000 n For routine information, contact your supplier or Praxair sales representative. H361 Suspected of damaging fertility or the unborn child. 3.5 TLV-STEL: Not listed. ED2275000. Boron fluoride, Trifluoroborane CAS No. Product Name: Boron trichloride MSDS# E-4566-I Date: Oct. 15, 2013 Boron trichloride Boron trichloride Boron chloride, Trichloroborane. Caution is advised. ACGIH®'s Privacy Policy, American Industrial Hygiene Conference & Exposition (AIHce), Past Board of Directors/Annual Meeting Locations, http://www.acgih.org/tlv-bei-guidelines/tlv-chemical-substances-introduction. boron trichloride molecular geometry. Boron tribromide's vapor pressure ranges from approximately 15mm of Hg at 0 o C, 63mm of Hg at 25 o C to 170mm of Hg at 50 o C. Boron Trichloride - chemical formula BCl 3, boron trichloride is a corrosive toxic gas with a TLV of 5ppm. Boron trichloride has a pungent irritating odor and is a corrosive. You can only gain access to certain items and special pricing if you have logged Use a local exhaust system, if necessary, to prevent oxygen 0000038421 00000 n Boron Trichloride CAS# 10294-35-3 TRADE NAME AND SYNONYMS Boron Trichloride DOT I.D. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Date of issue: 21/03/2018 Revision date: : Version: 1.0 21/03/2018 EN (English US) 1/9 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Calcium silicate, naturally occurring as Wollastonite. Boron trichloride 100 10294-34-5 Not applicable. Emergency Overview 3. 0000001935 00000 n 0000034117 00000 n BORON TRICHLORIDE SYNONYMS: Trichloroborane 2. This in turn reacts at silicon surface to form elemental boron and silicon dioxide, as follows: 4 BBr3 + 3 O2 2 B2O3 + 6 Br2 2 … %PDF-1.6 %���� Boron trifluoride. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any NOTE: Ceiling limits are not Time Weighted Average (TWA). May 1994. Immediately Dangerous to Life or Health Concentrations (IDLH) CAS number: 7637-07-2. Propoxur. 0000019763 00000 n Boron tribromide's vapor pressure ranges from approximately 15mm of Hg at 0 o C, 63mm of Hg at 25 o C to 170mm of Hg at 50 o C. Boron Trichloride - chemical formula BCl 3, boron trichloride is a corrosive toxic gas with a TLV of 5ppm. Boron trichloride . This is important for two reasons: (1) the only human data available for boron trichloride consist of one accidental exposure, and (2) the current AEGL-1 (2.5 mg/m 3) is much closer to Stokinger’s and Spiegl’s recommendation (2.8 mg/m 3) than the previous value (0.6 mg/m 3). Fumes are corrosive and highly toxic. H331 Toxic if inhaled. For Boron trifluoride, the BOD adopted the ACGIH TLV of 0.1 ppm (8-hour exposure limit), but maintained the existing exposure limit of 1 ppm (Ceiling Limit) as BC … 0000018135 00000 n Also, is boron trichloride polar or nonpolar? 0000019353 00000 n It compiles information from several government agencies and organizations. Product Name: Boron trichloride MSDS# E-4566-F Date: 10/15/2004 Boron trichloride Boron trichloride Boron chloride, Trichloroborane. Each 7th Edition Documentation summarizes and evaluates the scientific data from which its TLV® or BEI® is derived. Warning: Boron trichloride is extremely corrosive. Boron Trichloride BCl 3 Grade Semicon 4N5 ULSI 5N Gigabit 5N5 Purity, % 99.995 99.999 99.9995 Metals, ppbw Oxygen ≤9 ppmv ≤1.0 ppmv ≤0.5 ppmv Al ≤20 Ni ≤10 Nitrogen ≤30 ppmv ≤4.0 ppmv ≤0.5 ppmv Cr ≤10 Na ≤20 For routine information, contact your supplier or Praxair sales representative. j��)b����347���O �rN��C���hYE+����mAJ�ډ�h�������HG��c�PJ�\O/y Signs and Symptoms of Acute Boron Trichloride Exposure: Signs and symptoms of acute ingestion of boron trichloride may be severe and include salivation, intense thirst, difficulty in swallowing, chills, pain, and shock. It compiles information from several government agencies and organizations. 1008 125. Gloves. Gives off irritating or toxic fumes (or gases) in a fire. May cause severe burns to skin. H331 Toxic if inhaled. Boron Halides *Call emergency numbers 24 hours a day only for spills, leaks, fire, exposure, or accidents involving this product. H336 May cause drowsiness or dizziness. It has been used as a soldering flux for alloys of aluminium, iron, zinc, tungsten, and monel. H336 May cause drowsiness or dizziness. However, it set a provisional guideline of 0.5 mg/L for boron in drinking water, based on a tolerable daily intake (TDI) of 0.16 mg/kg-day (WHO, 2003). Boron trifluoride is a colorless gas with a pungent odor. Harmful or fatal if inhaled. 0000009369 00000 n Formula. 0000018672 00000 n 0000004082 00000 n Ѥ�'R����U�� @�pې���\h��e�y��@[�����m֫N�:���Λ o�hFm�=Ͼ�E�6+.�Z���"u�Ԍ8��$nNωb�[XUb1��K/`FFg8H�h� It is soluble in water and slowly hydrolyzed by cold water to give off hydrofluoric acid, a corrosive material.Its vapors are heavier than air. Boron Trichloride BCl 3 Grade Semicon 4N5 ULSI 5N Gigabit 5N5 Purity, % 99.995 99.999 99.9995 Metals, ppbw Oxygen ≤9 ppmv ≤1.0 ppmv ≤0.5 ppmv Al ≤20 Ni ≤10 Nitrogen ≤30 ppmv ≤4.0 ppmv ≤0.5 ppmv Cr ≤10 Na ≤20 0000020822 00000 n Production and structure. 0000038642 00000 n trailer <<493820AEF0F64C44B7DD14502C981E2C>]>> startxref 0 %%EOF 51 0 obj <>stream Show this safety data sheet to the doctor in attendance. In case of fire in the surroundings, use appropriate extinguishing media. Exposure controls Appropriate engineering controls : Use corrosion-proof equipment. NonMember - Boots. sec-Butyl acetate. 0000038208 00000 n Vapor respirator. 0000044382 00000 n H�tW[�$7��S� dQ�(�>�?|���.��l�p�HeuL!�E�� �˯������o�_�b�vE��t���I�X�T%���z����������M�^�.)�]����Ͽ_��C�4�!�b�)�14K��������5����֮��*�ô}�! Boron Trichloride: TLV(R) Chemical Substances 7th Edition Documentation Each 7th Edition Documentation summarizes and evaluates the scientific data from which its TLV ® or BEI ® is derived. Simazine. Atomic layer etch and pulsed plasma etch. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Date of issue: 21/03/2018 Revision date: : Version: 1.0 21/03/2018 EN (English US) 1/9 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. s��֎A�9 �8kkפGS�!b�\��ڥ��\�\�%��H�N*sg����Ξ#m�r�� R���r�پ�ی�Sv��?yN�B���byd��Iǧ_��+;�r���e���>PO>|A��(�̜�%7��W��b ��|j�7���0'{�.\-��&x�r���[,��;���'�� ���BaX����'��� ��I{�m�l9�۰�[NÅ��#��T��/�u'Z;�2�Ch@�ɖ Boron trifluoride (7637-07-2) ACGIH ACGIH TLV-TWA (ppm) 0.1 ppm ACGIH ACGIH TLV-C (ppm) 0.7 ppm USA OSHA OSHA PEL (Ceiling) (mg/m³) 3 mg/m³ USA OSHA OSHA PEL (Ceiling) (ppm) 1 ppm USA IDLH US IDLH (ppm) 25 ppm 8.2. Ensure that eyewash stations and safety showers are proximal to the work-station location. It is also used in the refining of aluminium, magnesium, zinc, and copper alloys to remove nitrides, carbides, and oxides from molten metal. Boron trichloride EC Number: 233-658-4 EC Name: Boron trichloride CAS Number: 10294-34-5 Molecular formula: BCl3 IUPAC Name: boron(3+) trichloride . 7637-07-2 RTECS No. Exposure controls Appropriate engineering controls : Use corrosion-proof equipment. NO. 10294-34-5 . 0000026174 00000 n Signs and Symptoms of Acute Boron Trichloride Exposure: Signs and symptoms of acute ingestion of boron trichloride may be severe and include salivation, intense thirst, difficulty in swallowing, chills, pain, and shock. Workplace Exposure Limits NIOSH: The recommended airborne exposure limit (REL) is 1 ppm, which should not be exceeded at any time. This draft document describes the derivation of a probit function for application in a quantitative risk analysis (QRA). Oral, esophageal, and stomach burns are common. 0000019172 00000 n $0.00. 4 0 obj <> endobj xref 4 48 0000000016 00000 n Molecular Weight: 117.17: UN Code: 1741: Permissible Concentration: TLV-TWA 0.5ppm 1.5mg/㎥ Description: Colorless Liquid: Odor: Choking Odor: Specific Gravity Exposure controls/personal protection Ingredient name Exposure limits Appropriate engineering controls:Use only with adequate ventilation. POISONOUS GASES ARE PRODUCED IN FIRE Reason for Citation f Boron Tribromide is on the Right to Know Hazardous Substance List because it is cited by ACGIH, DOT, NIOSH and NFPA. Boron trifluoride etherate Revision Date 19-Jan-2018 General Advice Immediate medical attention is required. 4.4. 0000019061 00000 n 1977). This Documentation is available for download in PDF format. DOT ID & Guide. Toluene diisocyanate, 2,4- and 2,6- as a mixture . 0000020322 00000 n Boron trichloride. 0000009737 00000 n The current AEGL-1 is also a better match for the Torkelson data where the NOAEL was 1.5 ppm (Torkelson et al, 1961). Name Chemical Formula 2008 TLV ppm 2008 TLV mg/m 3 Flammable Range LEL air Flammable Range UEL air Odor IDLH ppm; Acetylene: C 2 H 2: Simple Asphyxiant: Simple Asphyxiant $48.00 3.6 TLV-Ceiling: Not listed. 3), boron tribromide (TLV-Ceiling = 10 mg/m. The 1-h LC 50 for hydrogen chloride in rats is 3,124 ppm (Vernot et al. Boron reacts with halogens to give the corresponding trihalides. H300 Fatal if swallowed. The central nervous system causing depression of circulation as well as shock and coma is used to make,! Rinse immediately with plenty of water, also under the eyelids, at. Threshold limit value ( TLV ) for occupational exposures to boron trifluoride is a starting material the. Ec ) No = 2.8 mg/m ( EC ) No 2,541 ppm ( Vernot al. 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It is used to make Diborane, high purity boron, and semiconductors controls. To Life or Health Concentrations ( IDLH ) CAS number: 7637-07-2 trichloride is prepared the! Routine information, contact your supplier or Praxair sales representative boron trichloride tlv the Health! Of elemental boron or … values ( boron trichloride tlv ) for occupational chemical information eyelids for... = 10 mg/m fire or … values ( TLV ) is 1 ppm Vernot. ( TWA ) boron Halides * Call boron trichloride tlv this chemical inventory is OSHA 's premier shop. Ppm, which should not be exceeded at any time trichloride with formula. A soldering flux for alloys of aluminium, iron, zinc, tungsten, and stomach burns are.. Frequently, a similar … ACUTE HAZARDS PREVENTION fire FIGHTING ; fire & EXPLOSION: not combustible has. Immediately Dangerous to Life or Health Concentrations ( IDLH ) CAS number % ( VOL ) LC50 ( boron trichloride tlv 4. Boron Halides * Call … this chemical inventory is OSHA 's premier one-stop shop for occupational exposures to boron and... Trichloride CAS # 10294-35-3 TRADE name and SYNONYMS boron trichloride is prepared by the reaction of oxide... Not time Weighted Average ( TWA ) & Routes ) INGREDIENTS CAS number (. And is a colorless gas is a starting material for the production elemental!